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PolyurethanePolyurethanes are very versatile thermoset plastics that were originally developed for military use by Otto Bayer in the late 1930 s They are so versatile that they can be made into a compound as soft as bubble-gum or they can also be formed into compounds that are as hard as a soft metal This is why they are so common in our everyday life s Today a wide variety of polyurethanes are used for many different applications such as flexible polyurethanes are used to make sofas cushions carpet backs car seats Rigid foams are used for insulation in freezers refrigerators and roofs Many shoe companies also use tough elastomeric polyurethanes for shoe soles The auto industry also use polyurethanes for a variety of reasons including dashboards bumper covers moldings and fenders And these are just a few of the many use for polyurethanes The base material used to form polyurethane compounds is actually a by-product of the oil refining process The end product polyurethane is made with two basic ingredients a Isocyanate and Polyol This is shown in the reaction belowPolyurethane ReactionIsocyanate Polyol PolyurethaneH OR - NCO R - OH R - N - C - O - R Polyurethanes are produced by reacting an isocyanate and a polyol of various types Almost all commercial grade polyurethanes available are based on two different isocyanates TDI toluenediisocyanate and MDI methylenebisdiphenyl diisocyanate Both of these isocyanates give different properties to the polyurethane and have varying types of processing systems The polyol which is the other reactant in the polyurethane is available in three different types PTMEG polyetetramethylene ether glycol PPG polypropylene ether glycol and polyester There are other isocyanates and polyols that can be used in the manufacturing of polyurethanes but these are the most common This process is also the process that is used in making polyurethane foams The structural formula of a polyurathane monomer isOn the following page there is a
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